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AAWSAP DIRD, Ultracapacitors as Energy and Power Storage Devices, November 2010

U.S. Department of War · 2010-11-01 · 34 pages · text from the file's own layer

This Defense Intelligence Reference Document was prepared by the Defense Intelligence Agency's Defense Warning Office and dated 1 November 2010. It is one of a series of advanced technology reports produced under the Advanced Aerospace Weapons System Applications Program. The report reviews how ultracapacitors work, how they compare with batteries, their history and materials, and their commercial, military and aerospace uses. It concludes that new materials and cell designs will raise energy density and that the U.S. government must understand the devices' spectral signatures.

From the source:Release of 2026-09-18 Incident: 11/1/10, Las Vegas, Nevada. Released with redactions. This document is a Defense Intelligence Reference Document (DIRD), a technical reference format used by the Defense Intelligence Agency (DIA) to capture baseline knowledge on a specific topic for later analytic use. DIRDs are best understood as reference and synthesis products rather than as original research. It is one of 38 DIRDs produced under the Advanced Aerospace Weapon System Applications Program (AAWSAP) between 2009 and 2011. Because AAWSAP’s scope permitted a broad range of supporting topics, not every DIRD in the series directly concerns aerospace systems or future threat assessment. The following summary reflects the DIRD’s scope and framing at the time of writing and should not be read as implying current validation of the concepts discussed. This DIRD surveys ultracapacitors as high-power energy-storage devices and argues that their main value lies in extremely rapid charge and discharge, very long cycle life, and usefulness in systems that need short bursts of power rather than sustained energy delivery. The report explains how ultracapacitors differ from batteries, reviews the materials and cell designs that determine their performance, and emphasizes that they are especially useful for power stabilization, backup power, load leveling, regenerative braking, and other applications where fast energy transfer matters more than total stored energy. It also notes their drawbacks, including lower energy density, self-discharge, and voltage-management requirements that limit their usefulness as stand-alone replacements for batteries in many applications. The document presents ultracapacitors as a maturing and increasingly important technology whose most credible aerospace and military uses lie in pulsed-power, missile and munitions systems, electric propulsion support, and other hybrid power architectures rather than in long-duration primary energy storage.

  • p. 2 …a series of advanced technology reports produced in FY 2010 under the Defense Intelligence Agency, Defense…
  • p. 5 …The high capacitance is achieved by the enormously high surface area of the carbon electrodes compared…
  • p. 6 …Over the last 30 years, numerous advances have been made that have led to many uses…
  • p. 7 …higher voltage, in much the same manner as a battery. Recent advances in ultracapacitors have moved…
  • p. 11 …Advancements in the understanding of the electric double-layer and ultracapacitor behavior have led to better…
  • p. 14 …For these reasons, activated carbon is the traditional carbon of choice for ultracapacitor applications. Recent advances…
  • p. 15 …Graphene is another advanced carbon material that shows promise to providing increased capacitance. One of the…
  • p. 22 …Advanced carbons will provide better control over the pore size and distribution, leading to an expected…
  • p. 23 UNCLASSIFIED1/FOR 8ffl@IAL tt91! e"t I tuning the inner diameter may provide further enhancements…
  • p. 30 …Within the next 10 yea rs, ultracaps will beg in to see the incorporation of advanced…
  • p. 31 …the size of an iPhone with mostly voice activated functions. As depicted in Figure 16, advancements…
  • p. 32 …Advanced carbons show great promise to generate a carbon electrode with much higher capacitance than the…
  • p. 33 …Tuite, Get the Lowdown On Ultracapacitors; Electronic Design, Nov 2007. 23 D. Tuite, Get the Lowdown…
UNCLASSIFIED1fFOR 8ffl@IAL tt9! e"t I
Chapter 7: Endnotes
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5 EPCOS White Pa per on UltraCa p Tech nology
6 P. Simon, A. Burke, Na nostructu red Carbons: Double-Layer Ca pacita nce and More; ECS Interface, 17, Spr. 2008,
38-43
7 EPCOS Wh ite Pa per on UltraCap Tech nology
8 D. Tuite, Get t he Lowdown On Ultracapacitors; Electro nic Design, Nov 2007.
9 J. R. Miller, A. F. Burke, Electrochemica l Capa citors: Challenges and Opportu nit ies for Real-World Applications;
ECS I nterface, 17, Spr. 2008, 53-57
10 J. R. Miller, A. F. Burke, Electrochemical Capacitors: Cha llenges and Opportunit ies for Real-Worl d Applicati ons;
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LI J. R. Miller, A. F. Burke, Electrochemical Capacitors: Chal lenges and Opportunities for Rea l-World Applications;
ECS Interface, 17, Spr. 2008, 53-57
12 K. Naoi, P. Simon, New Materials and New Configurations for Advanced Electrochemical Capacitors; ECS
Interface, 17, Spr. 2008, 34- 37
13 Burke, Ultracapacitor Technolog ies and Application in Hybrid and Electric Vehicles; Internationa l Journal of
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14 J. R. Miller, P. Simon, Fu ndamentals of Electrochemical Capacitor Design and Operation; ECS Interface, 17, Spr.
2008, 31-33
15 P. Simon, A. Burke, Nanostructured Carbons : Double-Layer Capacitance and More; ECS Interface, 17, Spr. 2008,
38-43
16 EPCOS White Paper on UltraCap Technology
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Doub le Layer Capacitors, Phil . Trans. R. Soc . A, 368, 3457 (2010)
18 C. N. R. Rao, A. K. Sood, R. Voggu, K. S. Subrahmanyam, Some Novel Attributes of Graphene, J. Phys. Chem .
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20 J. Chm iola, G. Yush in, Y. Gogotsi, C. Portet, P. simon, P. L. Taberna, Anomalous I ncrease in Carbon Capacitance
at Pore Sizes Less than 1 Nanometer; Science, 313, 1760 (2006)
21 P. Simon, A. Burke, Nanostructured Carbons : Double-Layer Capacitance and More; ECS Interface, 17, Spr. 2008,
38-43
22 D. Tuite, Get the Lowdown On Ultracapacitors; Electronic Design, Nov 2007.
23 D. Tuite, Get the Lowdown On Ultracapacitors; Electron ic Design, Nov 2007.
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31 C. N. R. Rao, A. K. Sood, R. Voggu, K. S. Subrahmanyam, Some Novel Attributes of Graphene, J. Phys. Chem .
Lett. , 1, 572 (2010)
32 M. D. Stoller, S. Park, Y. Zhu, J. An, R. S. Ruoff, Graphene-Based Ultracapacitors, Nano Lett, 8, 3498 (2008)
33 M. D. Stoller, S. Park, Y. Zhu, J. An, R. S. Ruoff, Graphene-Based Ultracapacitors, Nano Lett, 8, 3498 (2008)
34 J. Chmiola, G. Yush in, Y. Gogotsi, C. Portet, P. simon, P. L. Taberna, Anomalous Increase in Carbon Capacitance
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35 D. Pech et al., J. Power Sources 195, 1266 (2010).
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28
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Official release, from the pursue collection. The PDF is mirrored here; the original link is above. 34 pages are in the text index: search them above, or from the library's search.