Documents / Report

Defense Intelligence Reference Document Ultracapacitors As Energy And Power Storage Devices

Defense Intelligence Agency · 34 pages · text from the file's own layer

This Defense Intelligence Reference Document from the Defense Intelligence Agency, dated 1 November 2010, was one of a series of advanced technology reports produced in FY 2010 under the Advanced Aerospace Weapons System Applications (AAWSA) Program. It reviews ultracapacitors as energy and power storage devices. It covers how they work, their materials, their commercial and military uses, and new developments such as carbon nanotubes, thin films and magnetic capacitors. It concludes that the U.S. government must understand and adopt advanced ultracapacitors.

  • p. 2 …a series of advanced technolo reports produced in FY 2010 under the Defense Intelligence Agency, (b…
  • p. 5 …The high capacitance is achieved by the enormously high surface area of the carbon electrodes compared…
  • p. 6 …Over the last 30 years, numerous advances have been made that have led to many uses…
  • p. 7 …higher voltage, in much the same manner as a battery. Recent advances in ultracapadtors have moved…
  • p. 11 …Advancements in the understanding of the electric double-layer and ultracapacitor behavior have led to better…
  • p. 14 …For these reasons, activated carbon is the traditional carbon of choice for ultracapacitor applications. Recent advances…
  • p. 15 …Graphene is another advanced carbon material that shows promise to providing increased capacitance. One of the…
  • p. 22 …Advanced carbons will provide better control over the pore size and distribution, leading to an expected…
  • p. 23 UNCLASSIFIED/ /P9Pl 8ffllilsl1k WE'lii QIU Y tuning the inner diameter may provide further enhancements. Figure…
  • p. 30 …Within the next 10 years, ultracaps will begin to see the incorporation of advanced carbon materials…
  • p. 31 …the size of an iPhone with mostly voice- activated functions. As depicted in Figure 16, advancements…
  • p. 32 …Advanced carbons show great promise to generate a carbon electrode with much higher capacitance than the…
  • p. 33 …Tuite, Get the Lowdown On Ultracapacitors; Electronic Design, Nov 2007. 23 D. Tuite, Get the Lowdown…
UNCLASSIFIED/ /P9Pl 8ffllilsl1k WE'lii QIU Y
tuning the inner diameter may provide further enhancements. Figure 7 shows a
vertically aligned CNT forest produced at Lockheed Martin's Advanced Technology
Center (LMATC). Lockheed Martin has worked with a number of catalysts and surfaces
to grow tailored CNT forests for a variety of applications. Select locations throughout
Lockheed Martin have been developing CNT-based technologies, utilizing vertically
aligned CNTs, CNTs dispersed onto surfaces, and CNTs dispersed into other media.
LMATC possesses expertise in CNT growth processes and characterization and has
capabilities for both materials development and ultracap testing. Lockheed Martin's
NEARLab facility produces CNT-coated glass fibers, which may provide a cost-effective
power storage solution that has structural elements built in. Ultracaps assembled from
CNT forests appear extremely promising for use in microelectronics.
Figure 7. CNT Forest. CNT forests grown in Lockheed Martin's laboratories can be tailored for specific sizes,
lengths, and densities.
Graphene is a relatively new discovery amongst carbonaceous materials. There are a
number of types of graphene that can be characterized by the number of layers of
graphene, the functionalization, or the oxidation status. Most graphene for
ultracapacitor applications is going to be few-layer graphene and large-area flakes. The
fewer the layers, the higher the active surface area will be. Single layer is ideal, but
manufacturing considerations make single layer difficult, even at the laboratory scale.
Functionalization will be directed toward improving capacitance or modifications to
enable battery-like performance.
Theoretical values of graphene indicate it could become an important material for the
next generation of ultracapacitors. Graphene may be used as the sole electrode
material, or it could be used as a conductive additive that also provides capacitance.
The surface area is calculated to be as high as 2,600 m 2/g, the thermal conductivity is
5,000 W/m·K, and the charge carrier mobility is 200,000 cm 2/V·s. High surface area
values and great conductivity are ideal properties for creating an electrode with very
high capacitance and extremely favorable rate capabilities. Reported capacitances
range from 135 to 205 F/g in aqueous electrolytes. 31 • 32 Figure 8 shows a transmission
electron microscope image of graphene flakes used for ultra capacitor electrodes. These
measurements come from few-layer graphene, rather than single layer, which suggest
18
UNCLASSIFIED//FQA Qffl8Itlit l!!l!H! &Ill I

Not linked to a story yet.

About this file

Report, from the dia collection. The PDF is mirrored here; the original link is above. 34 pages are in the text index: search them above, or from the library's search.